Just spend maybe $15-20 bucks, have some glass cut for you (leave about 1/8" gap on either side of the baffle), use some silicone, and you're done. It's very simple to do, and you won't have issues with anything. I forget the exact thickness, but I believe I used 3/16" thick for my 20 long sump. With time, the acrylic will bow unless you use 1/4" thick acrylic, which is basically the same cost as the glass anyway. However, acrylic to glass will never have the same quality bond as glass to glass. Stick with the material that your sump us made out of, and you're fine.
Having said that, at the end of the day, you're never going to get more than 11" depth out of a 20 long tank for a sump, so the psi hitting the seams won't ever be really strong anyway. Either acrylic or glass is fine, but I recommend glass so long as either material is thick enough.