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Did I kill 6 of my fish due to bad RODI Water?? (1 Viewer)

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SCUBAFreaky

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I got super busy with work over the summer to the point where my work-life balance was heavily off. As such, my tank got neglected. My corals were starting to show signs of unhappiness so I did a 25% water change (first H2O change since May) and tested my water. Calcium was super low and phosphates were super high. Ugh. I admit that I was a little aggressive on the calcium adjustments. I was raising my calcium levels by not quite 50 ppm per day to get it back up in the mid 300s. Two days after the water change 3 of my fish died...a pair of 3 stripe damsels and a Eibl's angelfish. I was really surprised. None of my fish were showing signs of stress that I noticed. In effort to keep reducing the phosphate level, I did another 25% water change a week later. Immediately all of my fish showed signs of major stress. Huh. What is going on?? I had chalked up the death of the first 3 fish to aggressive calcium additions. But this time I didn't do anything but the water change. Two days later my two 12 year old clownfish died along with my tomini tang. I'm still super bummed about my 12 year old clowns. They were the longest lived fish I've ever had. Sucks. If I didn't know any better I would have said the fish stress was either being caused by high ammonia or low oxygen. The overflow on my tank is an old school Durso drain, so lots of air exchange on the way to the sump. I'm also running a protein skimmer...also lots of gas exchange. Nothing has changed with either of those so likely not a gas exchange issue.

Before the first water change my inlet and outlet DI bed TDS was 5 and 0 ppm. After the 2nd water change my outlet DI TDS was now indicating 1 ppm and the bed color change was about 2/3s of the way up. I admit I didn't check the TDS when I made the 2nd batch of saltwater. Note, I use a single stage filter for my DI resin. I use the blue color changing resin from BRS. In trying to figure out what's going on with my tank I discovered the BRS Investigates video where Ryan shows that as DI beds reach end of life they can shed silica and ammonia. So did I possibly poison my fish with something shedding from my DI Resin bed?? I still have a batch of salt water I was going to use for a 3rd water change but hit the pause button while I figure out what caused my fish to die. I have since changed the DI Resin along with a particulate filter and carbon block as well. I don't have any sort of ammonia test kit. My tank has long since been cycled. I'm contemplating getting an ammonia test kit from Amazon and testing the batch of saltwater I still have and then I'll likely throw it out and not risk it.

Any other thoughts??
 

frankc

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I would definitely get an ammonia test kit to rule out that possibility, but other than that, I wouldn't think it would be the RODI water. I ran a mostly FOWLR tank for over 20 years, and even a reef tank for almost 1 year, using tap water and dechlorinator, and my first clownfish also lived 12 years. Most fish are not that sensitive to things like calcium and phosphate unless they are at extreme levels. I guess if the carbon block was completely exhausted and a bunch of chlorine got in there, that would be a problem. I hope you can figure it out.
 

Erin

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I'm sorry this is happening. I don't have any ideas to share but I hope things stabilize soon! What fish do you still have? Have inverts been affected too?
 

jrounding

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I use the BRS calcium calculator and it says you can do 50 ppm of calcium per day maximum so you are fine. I had the same issue with resin and that’s why I upgraded my system. 9 TDS coming out of the RO and then 9 TDS coming out of my resin, but my cartridge had not changed color. This has resulted in an green hair algae plaguing my tank. As the algae has been disappearing I’ve been seeing big calcium uptake. I assume this is choraline and my corals recovering. Typically calcium swings affect inverts more than fish. Fish are pretty hardy and adaptable to changing water conditions. So who really knows what happened. What I do know is I would dump that saltwater. Also if your top up tank is full of that water dump it too.
 

Cody

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To tag on Frank’s point, I don’t think it was the water or calcium adjustments. Maybe it was the salt, maybe a piece of equipment leached something into the water, etc.
 
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SCUBAFreaky

SCUBAFreaky

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What fish do you still have? Have inverts been affected too?
I have one fish left, a melanurus wrasse. He seems fine now. Doesn't seem to be breathing hard and comes out to eat every evening so far. Inverts also seem to be doing well. My corals aren't showing signs of being affected by whatever stressed and ultimately killed the fish. That's the real puzzler. Now, don't get me wrong, my corals are still struggling a little bit but I suspect that's due to the calcium still being on the low side and high phosphate.
Fish are pretty hardy and adaptable to changing water conditions. So who really knows what happened.
This has been my experience as well through the years so that's why I'm really stumped and reaching out to the group.
Also if your top up tank is full of that water dump it too.
Yep, totally agree. All the top off water has been replaced with water made from the newly installed filters. Didn't want to chance it while I attempt to sort this out.

Thanks for all of the thoughts so far! Please keep the brainstorming coming!
 
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