I took my 25 and just moved it to a 65G (a 58G but a little taller).
I filled up the entire 65G on Saturday and let it run until Tuesday when I did the switch. Then I emptied half the 25 and its contents into two rubber-made containers.
Make sure you get the detruis off the rocks. Dip each rock after you take it out of the tank in a bucket of tank water and get the detrius off. Detrius can cause water quality problems.
Use fresh sand and a cup full of your old sand.
I spent the next two hours transfering water between the two tubs and the old tank to get the water all the same. Then I put the LR from my old tank in and aquascaped. Then the fish went in.
This is the 25G about a month ago:
This is what I am working on now:
The left side is pretty much done. There are two rocks that are just two much on the shelf. On the right side I need to build over the shelf and in the middle I need to conect the two sides. Then some of the corals on the sand can go into the rock work. I wish my corals would have gone farther but its an excuse to buy more.
The rest of my rock was bought second hand since it was not from my tank I have been taking a few pieces every day and putting them in my sump. I measure the next day for water quality problems then aquascape the pieces into the tank. The other reason to aquascape slowly is that if you put all the rock in at one time you will end up with a rock wall. I have more rock than I need so I pick the best pieces to make the tank open and free. If you make a rock wall you won't be maximizing your light because the corals will be closer to the bottom.
Other issues are that I added more light VHO to Metal Halide. Unless you have been running carbon or doing water changes your water will be clearer which will give your corals more light. I kept the corals on the sand bed and have been slowly moving them up as they expand to the same size as they once were in the old tank.
Remember "Detrius is the Devil, Don't Put Old Poop in Your New Tank"